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Thermodynamics
First Law of Thermodynamics
GATE 2016
Medium

The INCORRECT statement about the characteristics of the critical point of a pure substance is that

  • Athere is no constant-temperature vaporization process
  • Bit has a point of inflection with zero slope
  • the ice directly converts from solid phase to vapor phase
  • Dsaturated liquid and saturated vapor states are identical

Explanation

Direct solid-to-vapor conversion is sublimation, which happens at the triple point region, not the critical point — so this statement is the incorrect one among the four. At the critical point, saturated liquid and vapor states merge into one, with zero-slope inflection and no distinct constant-temperature vaporization plateau.

Source: GATE ME 2016 Set-3 (2016)

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