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Thermodynamics
Entropy & Second Law
GATE 2012
Medium

An ideal gas of mass m and temperature T1 undergoes a reversible isothermal process from an initial pressure P1 to final pressure P2. The heat loss during the process is Q. The entropy change ΔS of the gas is

  • AmR ln(P2/P1)
  • mR ln(P1/P2)
  • CmR ln(P2/P1) − Q/T1
  • Dzero

Explanation

For a reversible isothermal process on an ideal gas, ΔS = mR ln(V2/V1). Since PV=constant at fixed T, V2/V1=P1/P2, so ΔS = mR ln(P1/P2). (This is fully consistent with ΔS=Q/T1 for a reversible process — the 'heat loss Q' given in the problem doesn't add new information, it's a consequence, not an independent input; option (D) is wrong because entropy of the GAS itself does change even though the universe's net entropy change is zero for a reversible process.)

Source: GATE ME 2012 (Booklet Code A) (2012)

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