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Process Calculations
Vapor-Liquid Equilibrium
GATE 2019
Medium

For a binary nonideal A-B mixture exhibiting a minimum boiling azeotrope, the activity coefficients γi (i=A,B) must satisfy

  • γA>1, γB>1
  • BγA<1, γB>1
  • CγA=1, γB=1
  • DγA<1, γB<1

Explanation

A minimum-boiling azeotrope arises from positive deviations from Raoult's law — both activity coefficients exceed 1.

Source: GATE CH 2019 (2019)

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