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Process Calculations
Vapor-Liquid Equilibrium
GATE 2019
Easy

For a single component system, vapor (g) and liquid (f) coexist in mechanical, thermal and phase equilibrium when

  • Aug=uf (equality of specific internal energy)
  • Bhg=hf (equality of specific enthalpy)
  • Csg=sf (equality of specific entropy)
  • gg=gf (equality of specific Gibbs free energy)

Explanation

Phase equilibrium (equal chemical potential in each phase, for a pure substance equal to specific Gibbs free energy) requires gg=gf.

Source: GATE CH 2019 (2019)

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