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Chemical Reaction Engineering
Reaction Kinetics
GATE 2016
Medium

A batch reactor shows CA decreasing exponentially from 1 to near 0, while CR and CS increase identically (single overlapping curve) toward a plateau of ~0.5. Which reaction scheme (rate constants in s⁻¹) matches?

  • AA⇌R (k=1,1) and A→S (k=1)
  • BA⇌R (k=3,3) and A⇌S (k=1,1)
  • A→R (k=1) and A→S (k=1)
  • DA→R (k=1) and A→S (k=3)

Explanation

CR=CS identically at all times requires equal, one-way (irreversible) rate constants to both products with no reverse reactions: A→R(k=1), A→S(k=1).

Source: GATE CH 2016 (2016)

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