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Chemical Technology
Organic Chemical Industries
GATE 2013
Medium

Match the reactant-product combination in Group 1 with the unit process in Group 2: (P) propylene-butanol, (Q) cumene-phenol, (R) butane-butadiene, (S) ethylene dichloride-vinyl chloride — (1) Pyrolysis, (2) Dehydrogenation, (3) Hydroformylation, (4) Peroxidation

  • AP-3, Q-2, R-4, S-1
  • BP-2, Q-4, R-3, S-1
  • CP-1, Q-3, R-2, S-4
  • P-3, Q-4, R-2, S-1

Explanation

Propylene is converted to butanol via the oxo (hydroformylation) process (P-3). Cumene is converted to phenol via the cumene (peroxidation) process (Q-4). Butane is dehydrogenated to butadiene (R-2). Ethylene dichloride is thermally cracked (pyrolyzed) to vinyl chloride monomer (S-1).

Source: GATE CH 2013 (2013)

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